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BestCrosswords.com - "It's Elemental" by Jim Walsh on 6/11/2007 [moderate]
Across 1- Practice boxing; 5- Paper purchase; 9- Birdhouses?; 14- Shoestring; 15- Napoleon's isle; 16- Indigenous Canadian; 17- And others: Abbr.; 18- Romanov ruler; 19- Dejected; 20- Chemistry class chart; 23- Adjudicated; 24- Nothing: Lat; 25- Consumer electronics maker; 28- Reject; 30- It follows you, sometimes; 31- Amateur radio operator; 32- Indonesian island; 35- George's brother; 37- One of the Canterbury pilgrims; 39- Muscat's land; 40- A type of mulled wine; 43- It can be sly or silly; 44- Slender and long-limbed; 46- Before, poetically; 47- Element number 79; 48- Giant's hall-of-famer Mel; 49- Provide weapons; 52- Fishhook feature; 54- U.S. federal medical. agency: Abbr; 55- African antelope; 57- Brewer's need; 61- Name given to metals that comprise group 2 on 20 across; 64- It can make your wishes come true; 66- Mideast chief: Var; 67- Leaves home?; 68- Bring out; 69- Himalayan bigfoot; 70- Make bread?; 71- Weighty books; 72- Yemeni port; 73- Some whiskeys;   Down 1- Got some shuteye; 2- Father: Lat; 3- A type of mite; 4- Soothing; 5- No longer working: Abbr.; 6- Hamlet setting; 7- You can count on them; 8- First First Lady; 9- More agile; 10- Hydroxyl compound: Chem; 11- Underdog, for example; 12- Draw; 13- Hog heaven?; 21- Keats creation; 22- Broadcast; 26- Quibble; 27- Revise; 29- Element number 50; 32- Element number 5; 33- Violinmaker Nicolò; 34- Element number 57; 36- Era; 38- Kitchen tool; 41- City dweller; 42- Red or Black; 45- Bronx bombers; 50- Scandinavian rug; 51- Country in Southeast Asia; 53- Deli loaf; 56- Treated the lawn; 58- Orderly grouping; 59- Cordwood measure; 60- At those times; 62- Vermin; 63- Dublin's home; 64- Obtain; 65- Tokyo, formerly;